all seems Perfectly normal!

Nakita flew down Rob's side and chased Phoenix (full menacing growl and jumped towards Phoenix but didn't make contact) approx. 3 metres out of the kitchen and then Nakita ran upstairs to hide under the bed
Here Nakita is teaching Phoenix that Rob is HER'S! The fact that she had no physical contact with Phoenix shows it was just a lesson.
- Phoenix fell asleep on the radiator, Nakita walked up to her cautiously but Phoenix woke up and both cats became tense, I separated them
Part 1 is good. Nakita initiated going up to Phoenix. BUT I would not have seperated them at that moment. Let them interact next time.

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I would keep allowing Phoenix out shile you are there to supervise, and seperate when you are away or asleep. Phoenix seems to be showing no signs of wanting to be dominant, which is good. Nakita will adjust. I guarrentee it!