Well, I am in the middle of nowhere on the outskirts of Phoenix. However... this is the vet that I use:

Ironwood Animal Hospital, Inc.
85 W Combs Rd
Suite 116
San Tan Valley, AZ 85140

Phone: 480-888-2299
Fax: 480-888-7683

They are open 24 hours for emergencies, and have regular office hours with less expensive office visit fees. So if you have a scheduled appointment, it will run a little less.
Every vet tech and vet I've seen at the practice has been very friendly.

They also have a larger, "friendlier" room that they use for when you are having to put one of your animals to sleep. I've been in that room twice - with my sweet Scooter Bug and with Oreo. They're really well staffed, and I am much happier than at my old vet office that closed down.