I can relate w/this situation, believe me. Before I began medicating my pee cats, I thought I was doomed to live in a giant litterbox. My males had pee wars and it just became maddening. I tried different meds to no avail until I found Clomicalm and it saved my house and my sanity and my cats from being rehomed. My vet feels Prozac is great for behavior problems but I've never tried it because my previous vet started them on Clomicalm and I've seen great success w/it. Some say it takes a while to start working but, in my case, it began working right away. However, if it ever stops, I won't hesitate to try Prozac. Anything is better than smelling urine all the time, having to wash clothes over again and scrubbing carpet on a daily basis. It got so bad here that Specs totally ruined a dining room server. He sprayed up against it so many times that it warped the door and I could no longer close it. (He's the one who got the pee wars started. All was fine until I brought him into the fold.) I now give them 5 mg. before bed, it keeps them calm but they're not drugged, they don't stagger around or anything, no side effects whatsoever and best of all, they don't pee everywhere. Oh and btw, it isn't just males. My female Yoda is part of the pee group. I have 4 of my 7 cats on Clomicalm.
If you decide against Prozac for your own reasons, ask your vet about Clomicalm. It's used mainly for behavior problems in dogs but has been used successfully in cats. It's been a lifesaver for me and for these pee cats, trust me. Hang in there, girl. There is help out there. You've just got to ask your vet about it. It isn't worth losing Richard over when it's so easily remedied.
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Unfortunatly, I don't know much about this, but like the others say, try a video camera first, or/and the Fluorescite, so you can find out who is peeing. 
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