If you don't clean all of the places he has sprayed with an enzyme cleaner, he will respray at the same spots. He will also spray if he is stressed or if there are other cats outside.
Use a cleaner such as Nature's Miracle or Outright's Simple Solution. Be sure to soak the area well and let it dry. The enzymes will 'eat' the odor while it dries.
My cats still anoint the house on occasion, mostly because of the above reasons and because I have what they consider "too many cats". Even the girls do it!
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