Oh yeah, LOTS of skunk experience here!
Tomato juice doesn't work very well.
Here is a great site, lots of interesting info THE SKUNK REMEDY PAGE

THIS WORKS. I've used this several years running, I keep enough fresh supplies on hand to whip up a couple batches as I seem to need them every spring

The Skunk Remedy Recipe-

Mix in a plastic bucket:

1 qt. of 3% peroxide
1/4 cup baking soda
1 to 2 teaspoons liquid soap (he recommends Softsoap or Ivory Liquid.
De-greasing dish soaps such a s Dawn don't work as well, and DO NOT use shampoo)

If you need to add water, add a little warm water to the mix.

Apply, leave on for 5 minutes (watch those eyes, it stings)

Rinse & repeat if necessary.

*edit* Here's my "Star" skunk catcher, last spring: