It could be as simple as Feline Acne. There are mild cases which are most common, then (as pictured in the second link) it can progress into very severe.
I have one that from time to time gets a very mild outbreak. The stuff is black and kind of waxy, I just keep bathing the area with warm water, it's very difficult to remove and the sores if there are any are under that. If there is a sore I use a small amount of neosporin on a q-tip, to help it heal. It can sometimes take weeks though. You have to keep at it if that is indeed what it is.
http://www.valleypetnews.com/felineacne.htm
(more severe in this link)
http://www.fabcats.org/acneandstudtail.html
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