The leave it command is a great command to teach for this & many other things too. It is pretty much only useful if your dog is getting close to the couch, once she jumps up on it I'd proabably use the "off" command.
The off command is great for when they jump on you or other objects. A lot of people make the mistake of saying down, to the dog down means lay down, so they get mighty confused when you say down to get off of something.
I agree with Irescue as far as the water technique goes. Also some dogs may like to be squirted with water. And also if you do decide to try it you'd have to make sure that the dog does not know that the squirt is coming from you, otherwise she'll know that if your not around or you don't have the squirt bottle in hand she can get up there. That doesn't really teach the dog anything it just prevents things from happening.
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