I've been present at numerous cat and dog births, and you really need do nothing. Momma should take care of everything, and it's best not to intervein unless absolutely necessary. When my Lhasa had her last litter, one of the pups was stillborn and I tried to revive it, but to no avail.
Make sure Momma cat has a nice birthing box or area, and definitely do not let the other cats stay with her while she is giving birth, or even after for that matter. Not only could it stress her, but could be dangerous for the babies. I don't know how much truth there is to this, but I have heard that a male cat will try to kill the babies - all except for a Siamese male. When my Siamese Momma had her kittens, my male Siamese would get in the box with the babies and babysit, so Momma could take a break.. but I still did not allow him near her while she was delivering, and for about a week after.
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