I'm mostly interested into animal welfare, so I was intrigued by your concept of post-adoption/breeder support

I've had a family member try this out (helping people find breeders), and it's usually not a good idea. The reason being is that you will get a myriad of bad breeders who can easily deceive you. Once that breeder is in your good favor, you're sending them a constant supply of customers. Also, reputable breeders don't often breed year round, so it's unlikely that you'll be able to find a perfect match for all of the prospective puppy buyers. It can be discouraging for both parties and the plan might even backfire! However, if you really want prospective buyers to meet breeders in person, direct them to the breed club of America and keep an updated book of performance events (agility shows, conformation shows, herding trials, lure coursing events, earthdog trials, etc). This will give them a chance to see what certain breeds are really like, without the possibility of endorsing a less-than-reputable breeder. All the benefits without the risks! =)
Have you thought about specializing in a certain area? I like holistic feed stores, but they're often too boutique-y and froo-froo for me. Maybe you could be the rare down-to-earth, straight-to-the-point pet shop that supplies holistic feed without all the lace and frills. Not that frills are a bad thing
ETA: I'm attaching the link of a chain feed store that really exceeds all standards. IMO, it's the epitome of a good, reliable pet store =)
http://petfoodexpress.com/petfood/index.asp
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