Welcome to PT Debbie! My name is Debbie also and Tubby & Peanut are my snots.
Everyone has different opinions on food, but I've been feeding T & P Science Diet since day on practically, and they are now 18 1/2 and 16 respecively, so it can't be all that bad. Since she is not a kitten anymore, the Science Diet Feline Maintenance would work well. You could just buy a smaller bag to make sure she likes it. I'll let the others answer the litter question because I'm in the process of switching myself and haven't found one I really like yet.
Does she still have all her claws? If so, you're definitely going to want to get a scratching post or some type of scratching "equipment." They also make the cardboard scratchers which are relatively cheap and can be replaced as often as needed. You might also want to consider a cat tree of some sort - if you have room for it - and several toys like catnip mice etc. She is going to need to have something to occupy her time while you're away. She will probably demand attention when you are home, so buy some toys that you can interact with her like the feather on a stick thing - Peanut loves that one.
And yes, you should probably cat proof to some degree, especially since you know she likes climbing on things, especially if you have any really valuable or treasured items. No matter how high up or how secure you think they are, she will get to them. Do this at least until you get to know her habits. Once she's been with you for awhile, you'll learn what you can leave out and what you can't. And expect her to get everywhere - including counter tops and on tables and the top of the refrigerator. There's just no getting away from this. Cats like to be up high and they like to jump and climb. Which is another reason for the cat tree. If you give her a nice place to climb - that has a view - it might keep her away from the other places.
Anyway, I could go on and on and on, but you'll get a lot of good advice from the others also, so I'll just say Welcome to Pet Talk and thanks so much for adopting an adult cat. She sounds like a real sweetie. Oh, and have you got a digital camera? If not, you'll need one of those because you'll need to be posting lots and lots of pictures of her here so we can all oooh and aaah over her with you.
Tubby
Spring 1986 - Dec. 11, 2004
RIP Big Boy
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Peanut
Fall 1988 - Jan. 24, 2007
RIP Snotty Girl
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Robin
Fall 1997 - Oct. 6, 2012
RIP Sweet Monkeyhead Girl
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